Hi there,
My advice would be to look at the stickies at the top of the page where you'll find so much info your head will be swimming! In the Useful Links sticky,
http://www.expatforum.com/expats/sp...ng-spain/2725-spanish-forms-useful-links.html
about the third post down, you'll find links to posts made about education, plus info about tax, cars, paperwork, websites, renting property and a big fat etc. Look at the other stickies too.
Happy reading, and ask if you need more info.